Author/Authors :
Pierres، نويسنده , , Camille and George، نويسنده , , Pascal and van Hijfte، نويسنده , , Luc and Ducep، نويسنده , , Jean-Bernard and Hibert، نويسنده , , Marcel and Mann، نويسنده , , André، نويسنده ,
Abstract :
A Brassard diene analogue was grafted on a modified Merrifield resin and used in a hetero Diels–Alder reaction with various aldehydes or ketones. The reaction gave access to 6-substituted 5,6-dihydropyrones (5a–u). This new immobilized electron-rich diene is more stable than the corresponding native diene, and is a versatile supported reagent.
Keywords :
solid supported reagent , hetero Diels–Alder , 6-dihydropyrones , 5
