Title of article
Zirconium-catalyzed enantiotopic group-selective synthesis of hydrindanes
Author/Authors
Mori، نويسنده , , Miwako and Takaki، نويسنده , , Tomoko and Makabe، نويسنده , , Muneyoshi and Sato، نويسنده , , Yoshihiro، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
3797
To page
3800
Abstract
When a THF solution of 12b and (S)-(EBTHI)ZrBINOL (10 mol%) was refluxed in the presence of BuMgCl (4 equiv.) for 4 h, zirconium-catalyzed enantiotopic group-selective cyclization proceeded and hydrindane 13b with 87% ee was obtained in 35% yield.
Keywords
zirconium-catalyzed cyclization , hydrindane , asymmetric synthesis , (EBTHI)ZrBINOL , enantiotopic group-selective synthesis , zirconacycle
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1662060
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