Author/Authors :
Wisnoski، نويسنده , , David D. and Leister، نويسنده , , William H. and Strauss، نويسنده , , Kimberly A. and Zhao، نويسنده , , Zhijian and Lindsley، نويسنده , , Craig W.، نويسنده ,
Abstract :
Microwave heating of high-loading TEMPO-methyl resin with functionalized styrenyl monomers in a SmithSynthesizer™ affords larger resin beads (>500 μm) via living free radical polymerization. Novel, high-loading Rasta resins (>5.5 mmol/g) are obtained ∼150 times faster than with conventional heating.