Author/Authors :
?valos، نويسنده , , Mart??n and Babiano، نويسنده , , Reyes and Cintas، نويسنده , , Pedro and D??az، نويسنده , , Jes?s and Hursthouse، نويسنده , , Michael B. and Jiménez، نويسنده , , José L. and Light، نويسنده , , Mark E. and L?pez، نويسنده , , Ignacio and Palacios، نويسنده , , Juan C.، نويسنده ,
Abstract :
This work describes the reactivity of 2-alkyl thioisomünchnones, exemplified here by the 2-methyl derivative, which behaves as nucleophile in the presence of both aliphatic and aromatic acid chlorides to give 2-heteroaryl ketones or 2-heteroaryl-1,3-diketones, respectively. However, 2-alkyl thioisomünchnones exhibit its characteristic 1,3-dipole behavior toward unsaturated systems.
Keywords :
Cycloadditions , 1 , 3-Dicarbonyl compounds , thioisomünchnones , mesoionics , tautomerism
