• Title of article

    Copper(I) tert-butoxide-promoted stereospecific alkylation of β-hydroxymethylvinylsilanes with alkyl halides

  • Author/Authors

    Taguchi، نويسنده , , Haruhiko and Tsubouchi، نويسنده , , C.Akira and Takeda، نويسنده , , Takeshi، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2003
  • Pages
    3
  • From page
    5205
  • To page
    5207
  • Abstract
    Stereospecific alkylation of (Z)-β-hydroxymethylvinylsilanes proceeded by treatment with copper(I) tert-butoxide and alkyl halides. Tri- and tetra-substituted allylic alcohols were obtained with complete retention of configuration.
  • Keywords
    silyl migration , Alkylation , copper(I) tert-butoxide , ?-silylallylic alcohol
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2003
  • Journal title
    Tetrahedron Letters
  • Record number

    1662904