Title of article :
Copper(I) tert-butoxide-promoted stereospecific alkylation of β-hydroxymethylvinylsilanes with alkyl halides
Author/Authors :
Taguchi، نويسنده , , Haruhiko and Tsubouchi، نويسنده , , C.Akira and Takeda، نويسنده , , Takeshi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2003
Abstract :
Stereospecific alkylation of (Z)-β-hydroxymethylvinylsilanes proceeded by treatment with copper(I) tert-butoxide and alkyl halides. Tri- and tetra-substituted allylic alcohols were obtained with complete retention of configuration.
Keywords :
silyl migration , Alkylation , copper(I) tert-butoxide , ?-silylallylic alcohol
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
