Title of article
Activation of 1-halonaphthalenes by electrogenerated [CoI-salen]−
Author/Authors
Faux، نويسنده , , Nadège and Labbé، نويسنده , , Eric and Buriez، نويسنده , , Olivier and Nédélec، نويسنده , , Jean Yves، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
5
From page
359
To page
363
Abstract
We report in this paper an electroanalytical study of the reaction of 1-halonaphthalenes with electrogenerated [CoI-salen]. With 1-iodonaphthalene, the reaction observed is a substitution, with a release of the iodide ion. Conversely, the reaction is much slower with 1-bromonaphthalene, and the intermediate adduct is observed at the time scale of cyclic voltammetry. The corresponding rate constants have been determined.
Keywords
salen , Cobalt , Kinetics , Aromatic halides
Journal title
Journal of Electroanalytical Chemistry
Serial Year
2007
Journal title
Journal of Electroanalytical Chemistry
Record number
1672820
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