Title of article :
Electrooxidation of tigogenin acetate
Author/Authors :
Morzycki، نويسنده , , Jacek W. and L?pez، نويسنده , , Yliana and P?oszy?ska، نويسنده , , Jolanta and Santillan، نويسنده , , Rosa and Siergiejczyk، نويسنده , , Leszek and Sobkowiak، نويسنده , , Andrzej، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2007
Abstract :
Electrooxidation of tigogenin acetate afforded two products: 3β-acetoxy-16β-hydroxy-23,24-dinor-5α-cholanoic acid lactone (2) and 20-epitigogenin acetate (3). The structure of the latter compound was confirmed by an X-ray analysis. The tentative mechanism of reaction is proposed.
Keywords :
Tigogenin , Electrochemical oxidation , Electrochemically-induced stereoisomerization , saponins
Journal title :
Journal of Electroanalytical Chemistry
Journal title :
Journal of Electroanalytical Chemistry
