Hydrogen Balmer α line behavior in Laser-Induced Breakdown Spectroscopy depth scans of Au, Cu, Mn, Pb targets in air

The behavior of hydrogen spectral emission of the plasmas obtained by Laser-Induced Breakdown Spectroscopy (LIBS) measurement of four metal targets (Au, Cu, Mn, Pb) in air was investigated. The plasma was produced by a pulsed Nd:YAG laser emitting in the fundamental wavelength. A systematic study of the spatial-integrated plasma emission obtained by an in-depth scanning of the target was performed for each metal, both in single pulse and collinear double-pulse configurations. Further, a spatial-resolved analysis of the emission of plasma produced on the Al target by a single laser pulse was performed, in order to describe the spatial distribution of emitters deriving from the target and air elements. The line intensities of the main plasma components (target metal, nitrogen, oxygen and hydrogen) were measured in both experimental conditions. Results show that the hydrogen line intensity varies greatly as a function of the metal considered, and exhibits a marked decrease after the first laser shots. However, differently from emission lines due to surface impurities, the hydrogen line intensity reaches a constant level deep inside the target. The spatial-resolved measurements indicate that hydrogen atoms in the plasma mainly derive from the target surface and, only at a minor extent, from the dissociation of molecular hydrogen present in the surrounding air. These findings show that the calculation of plasma electron number density through the measurement of the Stark broadening of hydrogen Balmer α line is possible also in depth scanning measurements.