Title of article
Configurational control in catalysis: Perspective on Hess et al., One-dimensional confinement in heterogeneous catalysis: Trapped oxygen on RuO2(110) model catalysts
Author/Authors
Schneider، نويسنده , , William F.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
2
From page
1351
To page
1352
Abstract
Recent experiments and kinetic Monte Carlo simulations reveal O adsorbates kinetically trapped at an RuO2(110) surface by Cl co-adsorbates. Cl decoration configurationally isolates O adsorbates, stabilizing them against O–O recombinative desorption to anomalously high temperature. The results illustrate how surface configurational effects can be exploited to tune heterogeneous reactivity.
Keywords
HCl oxidation , kinetic Models , lattice models , RuO2(110) , Heterogeneous catalysis , Mean-field
Journal title
Surface Science
Serial Year
2012
Journal title
Surface Science
Record number
1686737
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