Title of article
Study of the adsorption structure of NO on Pt(111) by scanning tunneling microscopy and high-resolution electron energy-loss spectroscopy
Author/Authors
Matsumoto، نويسنده , , Masuaki and Fukutani، نويسنده , , Katsuyuki and Okano، نويسنده , , Tatsuo and Miyake، نويسنده , , Kouji and Shigekawa، نويسنده , , Hidemi and Kato، نويسنده , , Hiroyuki and Okuyama، نويسنده , , Hiroshi and Kawai، نويسنده , , Maki، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
101
To page
105
Abstract
The structure of nitric oxide (NO) on a Pt(111) surface was studied by scanning tunneling microscopy (STM) and high-resolution electron energy-loss spectroscopy (HREELS). The coexistence of two species is observed by STM after saturating the surface with NO at 70 K and annealing to 215 K. Two pairs of NO and PtN stretching vibrational frequencies are observed in HREELS spectra after annealing, which are assigned to the two species observed by STM. Comparison between the spectra of HREELS and infrared absorption spectroscopy (IRAS) indicates that IRAS is less sensitive to the lower-frequency mode. A new model for the adsorption structure of NO on the Pt(111) surface is proposed and discussed.
Keywords
Electron stimulated desorption (ESD) , morphology , Platinum , nitrogen oxides , surface structure , Roughness , and topography , Chemisorption , Vibrations of adsorbed molecules , Scanning tunneling microscopy , Electron energy loss spectroscopy (EELS)
Journal title
Surface Science
Serial Year
2000
Journal title
Surface Science
Record number
1687824
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