Strong repulsion and site exclusion in a system with ontop and bridge sites on a one-dimensional lattice: equilibrium and kinetics

We derive the kinetics for an adsorbate with strong nearest neighbor repulsion and additional second neighbor lateral interactions, starting from a kinetic lattice gas model. We then make the connection with site exclusion, first, as a demonstration, for an adsorbate with one adsorption site and next with both top and bridge adsorption, to elucidate the principal effects on sticking coefficients and desorption spectra. This paper is restricted to one-dimensional systems.