Title of article :
Composition, structure, and sorbability of the thermally treated water deironing precipitate with respect to carbon monoxide
Author/Authors :
Novoselova، نويسنده , , L.Yu.، نويسنده ,
Abstract :
This work deals with studying the composition, structure, and sorbability of the water deironing precipitate sample thermally treated at 850 °C (WDP-850) with respect to carbon monoxide.
ing to the data of X-ray fluorescence (XRF) spectroscopy, WDP-850 contains 44.14% of iron, 6.29% of silicon, and 34.78% of oxygen.
sults of X-ray diffraction (XRD) analysis indicate the presence of Fe2O3, Fe3O4, and SiO2 nanocrystallites (~ 11.4, 30.6, and 8.0%, respectively).
udies performed via the temperature-programmed desorption of CO show that WDP-850 can sorb carbon monoxide at 25 and 200 °C.
mposition and structure of the precipitate sample obtained after CO adsorption at 200 °C (WDP-850-CO) have also been studied.
ing to XRD data, nearly 9.3% of the silicon carbide (SiC) phase with the moissaniteʹs structure has appeared in the material.
C phase is supposed to result from the dissociative adsorption of CO on the surface of WDP-850.
been concluded that WDP can be used as a base for the synthesis of functional materials, for example, CO sorbents.
Keywords :
nanocrystallites , Fe2O3/Fe3O4/SiO2/SiC , Sorbents , Water deironing precipitate