Author/Authors :
Blomberg، نويسنده , , S. and Gustafson، نويسنده , , J. and Martin، نويسنده , , N.M. and Messing، نويسنده , , M.E. and Deppert، نويسنده , , K. and Liu، نويسنده , , Z. and Chang، نويسنده , , R. and Fernandes، نويسنده , , V.R. and Borg، نويسنده , , A. and Grِnbeck، نويسنده , , H. and Lundgren، نويسنده , , E.، نويسنده ,
Abstract :
PdAg nanoparticles with a diameter of 10 nm have been generated by an aerosol particle method, and supported on a silica substrate. By using a combination of X-ray Energy Dispersive Spectroscopy and X-ray Photoelectron Spectroscopy it is shown that the size distribution of the particles is narrow and that the two metals form an alloy with a mixture of 75% Pd and 25% Ag. Under oxidizing conditions, Pd is found to segregate to the surface and a thin PdO like oxide is formed similar to the surface oxide previously reported on extended PdAg and pure Pd surfaces.
Keywords :
PdAg , Alloy , Nanoparticles , HPXPS