Title of article :
Local order of Ag in AgI–Ag2MoO4 glasses: an EXAFS study
Author/Authors :
Ghigna، نويسنده , , Paolo and Muri، نويسنده , , Melissa Di and Mustarelli، نويسنده , , Piercarlo and Tomasi، نويسنده , , Corrado and Magistris، نويسنده , , Aldo، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Abstract :
Silver iodomolybdates are under investigation in order to define a transport model for AgI-based oxide glasses. In this paper we report a preliminary EXAFS study on a glass of composition 0.66AgI:0.33Ag2MoO4. The EXAFS Fourier transform shows two peaks that are attributed to the coordination with oxygen (Ag–O distance 2.38(1) Å, coordination number 1.5(3)) and iodine (Ag–I distance 2.830(5) Å, coordination number 1.5(3)), respectively. The present coordination numbers confirm our previous 109Ag NMR results.
Keywords :
EXAFS , Ag-K edge , AgI , Glasses , Molybdate
Journal title :
Solid State Ionics
Journal title :
Solid State Ionics
