Title of article
Epoxidation of indene by chloroperoxidase
Author/Authors
Manoj، نويسنده , , Kelath M and Lakner، نويسنده , , Frederick J and Hager، نويسنده , , Lowell P، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
5
From page
107
To page
111
Abstract
The stereochemistry of the chloroperoxidase-catalyzed epoxidation of indene has been elucidated. In aqueous solution the intial epoxide product is not stable and opens to form the cis-trans diols. When the reaction was carried out in the absence of water, the epoxide enantiomers could be isolated. Under these conditions in 1R2S enantiomer was formed in approximately 30% ee.
Keywords
indene , Chloroperoxidase , epoxidation
Journal title
Journal of Molecular Catalysis B Enzymatic
Serial Year
2000
Journal title
Journal of Molecular Catalysis B Enzymatic
Record number
1708465
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