Title of article :
First enzymatic resolution of a phosphane–borane complex
Author/Authors :
Faure، نويسنده , , Bruno and Iacazio، نويسنده , , Gilles and Maffei، نويسنده , , Michel، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The borane adduct of (2-hydroxypropyl)diphenylphosphane 1 was resolved by enantioselective esterification with CAL-B. (S)-1 was thus obtained with 91% enantiomeric excess. Its absolute configuration was determined by chemical correlation from (S)-propylene oxide.
Keywords :
(S)-propylene oxide , Chiral organophosphorus compounds , phosphane–borane complexes , CAL-B , enzymatic resolution
Journal title :
Journal of Molecular Catalysis B Enzymatic
Journal title :
Journal of Molecular Catalysis B Enzymatic
