Author/Authors :
Nakamura، نويسنده , , Koichi and Moriga، نويسنده , , Toshihiro and Sumi، نويسنده , , Akiyoshi and Kashu، نويسنده , , Yoshihiro and Michihiro، نويسنده , , Yoshitaka and Nakabayashi، نويسنده , , Ichiro and Kanashiro، نويسنده , , Tatsuo، نويسنده ,
Abstract :
The temperature dependence of the 7Li–NMR line width of LiCuO2 was measured. The line widths were constant at low temperature, while a narrowing in the line widths was observed above 370 K. The results are explained by a model of thermally activated diffusion of Li+ ions. The activation energy for the Li+ ionic diffusion was estimated to be 0.23 eV in LiCuO2, being lower than that in LiCoO2. It indicates that the fast ionic diffusion occurs in LiCuO2.