Title of article :
Study on controlled free-radical polymerization in the presence of 2-cyanoprop-2-yl 1-dithionaphthalate (CPDN)
Author/Authors :
Zhu، نويسنده , , Jian and Zhu، نويسنده , , Xiulin and Cheng، نويسنده , , Zhenping and Liu، نويسنده , , Feng and Lu، نويسنده , , Jianmei، نويسنده ,
Issue Information :
دوهفته نامه با شماره پیاپی سال 2002
Abstract :
Polymerization of methyl methacrylate was carried out in the presence of 2-cyanoprop-2-yl 1-dithionaphthalate (CPDN). The results exhibit controlled polymerization characters: well-controlled molecular weight, narrow polydispersity (minimal value: 1.09), molecular weight linearly increasing with conversion and first-order kinetics of polymerization. The polymer can be used to synthesize methyl methacrylate–styrene copolymer with narrow polydispersity (minimal value: 1.22). The polymers were characterized by 1H NMR and GPC. The effect of molar ratio among MMA/CNDB/AIBN on polymerization was investigated.
Keywords :
Controlled polymerization , 2-cyanoprop-2-yl 1-dithio naphthalate (CPDN) , Reversible addition fragmentation transfer reactions
