• Title of article

    Block and star block copolymers by mechanism transformation. VIII Synthesis and characterization of triblock poly(LLA-b-St-b-MMA) by combination of ATRP and ROP

  • Author/Authors

    Tao، نويسنده , , Lei and Luan، نويسنده , , Bin and Pan، نويسنده , , Cai-yuan، نويسنده ,

  • Issue Information
    دوهفته نامه با شماره پیاپی سال 2003
  • Pages
    8
  • From page
    1013
  • To page
    1020
  • Abstract
    Block copolymers, poly(LLA-b-St)s and triblock copolymes, poly(LLA-b-St-b-MMA)s have been synthesized by the combination of the atom transfer radical polymerization (ATRP) with ring-opening polymerization (ROP) using bifunctional initiator β-hydroxylethyl α-bromoisobutyrate (HEBIB) without intermediate function transformation. The molecular weight (MW) and the molecular weight distribution (MWD) can be controlled. The structures of the copolymers were confirmed by 1H NMR spectroscopy and GPC.
  • Keywords
    Bifunctional initiator , Block copolymer , atom transfer radical polymerization
  • Journal title
    Polymer
  • Serial Year
    2003
  • Journal title
    Polymer
  • Record number

    1719178