Title of article
The kinetics of vinyl acrylate photopolymerization
Author/Authors
Lee، نويسنده , , Tai Yeon and Roper، نويسنده , , Todd M and Jonsson، نويسنده , , E.Sِnny and Kudyakov، نويسنده , , Igor and Viswanathan، نويسنده , , K and Nason، نويسنده , , C and Guymon، نويسنده , , C.A and Hoyle، نويسنده , , C.E، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2003
Pages
7
From page
2859
To page
2865
Abstract
The photopolymerization of vinyl acrylate has been investigated using real-time FTIR. The acrylate and vinyl groups exhibit different polymerization kinetics with the acrylate functionality polymerizing at a much faster rate. Vinyl acrylate not only self-initiates its own free-radical polymerization, but also photoinitiates the polymerization of mono- and difunctional acrylates. Kinetic studies using a model monomer system indicate that it is essential for the acrylate and vinyl group to be part of the same molecule in order to function as an effective initiator for acrylate polymerization.
Keywords
Photopolymerization , Photoinitiation , Vinyl acrylate
Journal title
Polymer
Serial Year
2003
Journal title
Polymer
Record number
1719618
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