Title of article
Synthesis and cationic photopolymerization of a new fluorinated oxetane monomer
Author/Authors
Sangermano، نويسنده , , M. and Bongiovanni، نويسنده , , R. and Malucelli، نويسنده , , G. and Priola، نويسنده , , A. and Thomas، نويسنده , , R.R. and Medsker، نويسنده , , R.E. and Kim، نويسنده , , Y. and Kausch، نويسنده , , C.M.، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2004
Pages
7
From page
2133
To page
2139
Abstract
A new fluorinated oxetane monomer (FOX) was prepared using a fluorinated alcohol by phase transfer catalysis in a Williamson ether synthesis. The new fluorinated monomer was used in cationic photopolymerization as comonomer of 3,3′-[oxydi(methylene)]bis(3-ethyloxetane). The presence of the FOX monomer induces a decrease of the glass transition temperature, thermal stabilization and an increase of the final oxetane group conversion. Completely hydrophobic surfaces were obtained with a selective enrichment of the fluorinated comonomer, as confirmed by contact angle and XPS analysis.
Keywords
Fluorinated oxetane , Cationic photopolymerization , Surface properties
Journal title
Polymer
Serial Year
2004
Journal title
Polymer
Record number
1721329
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