Title of article
Polymerization strategies to overcome limiting monomer conversion in silicone-acrylic miniemulsion polymerization
Author/Authors
Rodrيguez، نويسنده , , Raquel and Barandiaran، نويسنده , , Marيa J. and Asua، نويسنده , , José M.، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2008
Pages
6
From page
691
To page
696
Abstract
The limiting conversion phenomenon observed in high solid content silicone-modified acrylic miniemulsion polymerizations was investigated. It was found that the limiting conversion was mainly due to the formation of inactive radicals upon propagation of butyl acrylate radicals with the vinyl end groups of the polydimethylsiloxane. Polymerization strategies that allowed overcoming this problem and achieving high monomer conversion were implemented.
Keywords
Miniemulsion polymerization , Silicone-acrylic , Limiting conversion
Journal title
Polymer
Serial Year
2008
Journal title
Polymer
Record number
1731256
Link To Document