Synthesis and characterization of highly refractive polyimides derived from 2,7-bis(4′-aminophenylenesulfanyl)thianthrene-5,5,10,10-tetraoxide and aromatic dianhydrides

New polyimides (PIs) containing thioether and sulfonyl groups in their main chains have been developed. These PIs were synthesized by a two-step polycondensation procedure from several dianhydrides such as 4,4′-[p-thiobis(phenylenesulfanyl)] diphthalic anhydride (3SDEA), 4,4′-oxydiphthalic anhydride (ODPA), 4,4′-[sulfonylbis(phenylenesulfanyl)] diphthalic anhydride (pDPSDA) and a new sulfonyl and sulfur-containing aromatic diamine, 2,7-bis(4′-aminophenylenesulfanyl)thianthrene-5,5,10,10-tetraoxide (APTTT). All of the PIs show good thermal and optical properties such as optical transparency higher than 80% at 450 nm for a thickness of ca. 10 μm, glass transition temperatures higher than 250 °C, thermal decomposition temperatures (T10%) in the range of 504–514 °C. Because of the two sulfonyl groups at each monomer unit in the polymer main chain, all of the PIs show good transparency maintaining relatively high refractive index.