• Title of article

    Low bandgap polymers with benzo [1,2-b:4,5-b′] dithiophene and bisthiophene-dioxopyrrolothiophene units for photovoltaic applications

  • Author/Authors

    Zhang، نويسنده , , Guobing and Fu، نويسنده , , Yingying and Xie، نويسنده , , Zhiyuan and Zhang، نويسنده , , Qing، نويسنده ,

  • Issue Information
    دوهفته نامه با شماره پیاپی سال 2011
  • Pages
    7
  • From page
    415
  • To page
    421
  • Abstract
    New donor/acceptor polymers PBDTTPT1 and PBDTTPT2 with alternating benzodithiophene (BDT) and bisthiophene-dioxopyrrolothiophene (TPT) units were synthesized by Stille coupling reaction. The polymers had optical bandgaps of 1.78 and 1.82 eV, and HOMO energy levels of −5.30 and −5.35 eV for PBDTTPT1 and PBDTTPT2, respectively. Polymeric solar cell devices based on these copolymers as donors and PC71BM as acceptor showed the highest open circuit voltage of 0.95 V and power conversion efficiency of 2.68% under the illumination of AM 1.5, 100 mW/cm2.
  • Keywords
    polymer solar cells , 2-b:4 , 5-b?] dithiophene , conjugated polymer
  • Journal title
    Polymer
  • Serial Year
    2011
  • Journal title
    Polymer
  • Record number

    1736857