Author/Authors :
Luong، نويسنده , , Nguyen Dang and Hippi، نويسنده , , Ulla and Korhonen، نويسنده , , Juuso T. and Soininen، نويسنده , , Antti J. and Ruokolainen، نويسنده , , Janne and Johansson، نويسنده , , Leena-Sisko and Nam، نويسنده , , Jae-Do and Sinh، نويسنده , , Le Hoang and Seppنlن، نويسنده , , Jukka، نويسنده ,
Abstract :
In this study, polyimide/graphene nanocomposite films which exhibited significant enhancements in mechanical properties and electrical conductivity were successfully fabricated. Graphene oxide (GO) synthesized by Hummer’s method was chemically modified with ethyl isocyanate to give ethyl isocyanate-treated graphene oxide (iGO), which is readily dispersed in N,N′-dimethylformamide (DMF). The iGO dispersion in DMF was then used as media for synthesis of polyimide/functionalized graphene composites (PI/FGS) by an in situ polymerization approach. It was shown that addition of only 0.38 wt% of FGS, Young’s modulus of the PI/FGS composite film was dramatically increased from 1.8 GPa to 2.3 GPa, which is approximately 30% of improvement compared to that of pure PI film, and the corresponding tensile strength was increased from 122 MPa to 131 MPa. In addition, the electrical conductivity of the PI/FGS with this graphene content was increased by more than eight orders of magnitude to 1.7 × 10−5 S m−1.
