Author/Authors :
Chien، نويسنده , , Hung-Chung and Tsai، نويسنده , , Li-Duan and Kelarakis، نويسنده , , Antonios and Lai، نويسنده , , Chien-Ming and Lin، نويسنده , , Jiunn-Nan and Fang، نويسنده , , Jason and Zhu، نويسنده , , Chao-Yuan and Chang، نويسنده , , Feng-Chih، نويسنده ,
Abstract :
The incorporation of highly porous activated carbon (aC) to Nafion membranes confers unprecedented levels of water uptake (4 times higher for 10 wt% aC compared to neat Nafion) at a minimal dimensional swelling and results in dramatic enhancements in ionic conductivity at low relative humidity. This behavior reveals the development of a robust network of water nanochannels formed by the carbon pores and the polymeric ionic domains which are structurally stabilized by the rigid Nafion backbone and the non-deformable aC particles.