Author/Authors :
Zang، نويسنده , , Yu and Nakao، نويسنده , , Kazuki and Yotsuyanagi، نويسنده , , Hiroki and Aoki، نويسنده , , Toshiki and Namikoshi، نويسنده , , Takeshi and Tsutsuba، نويسنده , , Toyokazu and Teraguchi، نويسنده , , Masahiro and Kaneko، نويسنده , , Takashi، نويسنده ,
Abstract :
By using a new achiral phenylacetylene having bulky substituents as a monomer, living-like helix-sense-selective polymerization (HSSP) has been achieved. This is the first example of the HSSP of substituted acetylenes where the degree of polymerization was controlled. The resulting one-handed helical living polymer initiated polymerization of a second monomer to successfully yield a block copolymer.
