• Title of article

    1H NMR study of dynamical inequivalence of cations in [C(NH2)3]3Sb2Cl9

  • Author/Authors

    Grottel، K. نويسنده , , M. and Paj?k، نويسنده , , Z. and Zaleski، نويسنده , , J.، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2001
  • Pages
    4
  • From page
    119
  • To page
    122
  • Abstract
    The proton NMR second moment and spin–lattice relaxation time have been studied for polycrystalline tris-guanidinium nonachlorodiantimonate(III) in a wide temperature range. The C3 reorientation of two types of the cations, hindered by very different potential barriers (20.5 and 54.5 kJ/mol) has been revealed. An unusually large dynamical inequivalence of two cations evidently reflects their different crystalline environments.
  • Keywords
    E. Nuclear magnetic resonance , A. Organic crystals
  • Journal title
    Solid State Communications
  • Serial Year
    2001
  • Journal title
    Solid State Communications
  • Record number

    1761639