Photo-induced changes in magnetization of GdBaCo2O5+δ

We report a study of the effect of red light (λ=650 nm) on the magnetic properties of GdBaCo2O5+δ. The ferromagnetic transition temperature decreases by 4 K and the intermediate to high spin state transition temperature increases by 3 K. We propose that electron capture in the oxygen vacancy along Co–O chain and competing interaction between the orbital ordering and ferromagnetic phase are responsible for the above observed results. A ‘butterfly-wing’ shaped hysteresis loop along with a field induced transition has been observed in the temperature window 190≤T≤215 K.