Hyperfine magnetic field at Ta impurities in nickel: Perturbed angular correlation and first principle calculation study

The hyperfine magnetic field ( H h f ) in 0.2 at.% Hf–Ni alloy is measured at the 181Ta probe using the time-differential perturbed angular correlation (TDPAC) method, in the temperature range 78–675 K. The obtained value of 8.6 (3) T at room temperature is in good agreement with the previously reported measurements for similar Hf concentrations in Ni. X-ray powder diffraction (XRPD) experiments confirmed that small atomic concentrations of Hf atoms (<1 at.%) mainly substitute on Ni lattice sites in the fcc crystal lattice without forming any intermetallic phase. In addition, ab-initio calculation using all-electron augmented plane waves plus local orbitals (APW+lo) formalism is performed and the obtained result for the hyperfine magnetic field at Ta site is in accordance with the measurement.