• Title of article

    Symmetry breaking by the heme pocket in horseradish peroxidase as revealed by Stark spectroscopy

  • Author/Authors

    Kِhler، نويسنده , , Cyprian M. and Friedrich، نويسنده , , J. M. Balog، نويسنده , , E. and Fidy، نويسنده , , J.، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 1997
  • Pages
    6
  • From page
    417
  • To page
    422
  • Abstract
    We performed hole-burning Stark effect experiments on Mg-substituted horseradish peroxidase and its complex with naphthohydroxamic acid. For comparison we also investigated Mg-mesoporphyrin in an ethanol/glycerol glass. The results demonstrate that the inversion symmetry of the porphyrin ring is broken by the protein environment.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    1997
  • Journal title
    Chemical Physics Letters
  • Record number

    1771383