Author/Authors :
Zweygart، نويسنده , , W. and Bittl، نويسنده , , R. and Wieghardt، نويسنده , , K. and Lubitz، نويسنده , , W.، نويسنده ,
Abstract :
X- and Q-band EPR and 55Mn cw-ENDOR experiments are reported on a binuclear oxo-bridged dimanganese MnIII MnIV complex. Consistent simulations of spectra from both frequency bands using one parameter set for the orthorhombic g tensor and MnIII and MnIV hyperfine tensors are achieved. Information on the manganese hyperfine couplings is independently obtained from 55Mn cw-ENDOR spectroscopy performed on both ions.
