Author/Authors :
Lalo، نويسنده , , C. and Deson، نويسنده , , J. and Gedeon، نويسنده , , A. and Fraissard، نويسنده , , J.، نويسنده ,
Abstract :
Laser-induced fluorescence spectra of quinoline adsorbed on different forms of acidic Y zeolite reveal interactions between the adsorbate and different polarizing sites in the supercages. Brّnsted acid sites protonate quinoline whereas Lewis acid sites appear to give a charge-transfer complex whose fluorescence is strongly red-shifted compared to that of the quinolinium ion. An unstable hydrogen-bonded complex is formed with non-acidic silanol groups.
