Title of article :
Eigenvalue problem formulation of coupled-cluster expansions through intermediate Hamiltonians
Author/Authors :
Nebot-Gil، نويسنده , , I and Sanchez-Marin، نويسنده , , J and Heully، نويسنده , , J.L. and Malrieu، نويسنده , , J.P and Maynau، نويسنده , , D، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 1995
Pages :
5
From page :
45
To page :
49
Abstract :
Using the intermediate Hamiltonian formalism, it is shown that coupled-cluster doubles (CCD) or singles and doubles (CCSD) may be formulated as an eigenvalue problem by dressing properly the doubles or singles and doubles configuration interaction matrix. The dressing may be either diagonal or non-diagonal. The so-formulated CC method converges even in nearly degenerate situations where the traditional set of coupled equations faces usually divergent behaviour.
Journal title :
Chemical Physics Letters
Serial Year :
1995
Journal title :
Chemical Physics Letters
Record number :
1772783
Link To Document :
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