Effect of the molecular dynamics of exchanging groups on electron transport. Stochastic Liouville equation approach

We developed a theory of nonadiabatic electron transfer reactions in the systems where conformational variations are present. This is done with the use of the stochastic Liouville equation approach. The conformational changes of the system are described as a two-state jump Markov process. Limiting regime analytic results for rate constants are presented for high and slow Markovian modulation.