Title of article
Rotationally resolved A 2Πu←X 2Πg electronic spectrum of tetraacetylene cation
Author/Authors
Pfluger، نويسنده , , David and Motylewski، نويسنده , , Tomasz and Linnartz، نويسنده , , Harold and Sinclair، نويسنده , , Wayne E. and Maier، نويسنده , , John P.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
7
From page
29
To page
35
Abstract
The rotationally resolved A 2Πu←X 2Πg electronic origin band spectrum of tetraacetylene cation (HC8H+) and its deuterated derivative (DC8D+) has been recorded in the gas phase, applying both frequency modulation spectroscopy in a liquid nitrogen cooled hollow cathode discharge and cavity ringdown spectroscopy in a supersonic planar plasma. The combined analysis of the rotational structure yields accurate molecular constants for the ground and electronically excited states as well as information on the molecular geometry.
Journal title
Chemical Physics Letters
Serial Year
2000
Journal title
Chemical Physics Letters
Record number
1773380
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