Title of article
Time-dependent variational principle with constraints
Author/Authors
Ohta، نويسنده , , Katsuhisa، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
7
From page
248
To page
254
Abstract
The time-dependent variational principle in the stationary action principle form is formulated with not only the normalization but also general constraint conditions for wavefunctions. The constraint conditions are classified into the first and the second classes as in Diracʹs constrained classical-mechanics. The Lagrange multipliers for the second-class constraints are uniquely determined by the consistency conditions. The normalization condition, as the first-class constraint, is supplemented with an adequate gauge-fixing function. As one of the applications, the quantum dynamics in subspaces based on the TDVP is suggested.
Journal title
Chemical Physics Letters
Serial Year
2000
Journal title
Chemical Physics Letters
Record number
1773496
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