Title of article
Why density augmentation occurs in dilute supercritical solutions
Author/Authors
Ruckenstein، نويسنده , , Eli and Shulgin، نويسنده , , Ivan L.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
7
From page
551
To page
557
Abstract
The conventional explanation of the density augmentation in a supercritical solvent, observed spectroscopically when a small amount of a solute was added, involved the clustering of the solvent about individual solute molecules. Here it is suggested that the augmentation is not caused by the solute, but rather it is due to the preexisting near critical fluctuations in the pure solvent and the preference of the solute for the high density regions of the supercritical solvent. It is also shown that the local composition of the solute molecules about a solute molecules is enhanced compared to its bulk composition.
Journal title
Chemical Physics Letters
Serial Year
2000
Journal title
Chemical Physics Letters
Record number
1773880
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