• Title of article

    A semiclassical correlation function approach to barrier tunneling

  • Author/Authors

    Grossmann، نويسنده , , Frank and Heller، نويسنده , , Eric J.، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 1995
  • Pages
    6
  • From page
    45
  • To page
    50
  • Abstract
    A time domain approach employing the semiclassical approximation to the quantum mechanical propagator, as applied to Gaussian wavepackets, is used to study the barrier penetration problem. We have observed that qualitative agreement with the exact quantum calculations for the correlation function and the transmission probability can be achieved by considering only classically allowed trajectories. The results slowly tend to the classical step function at the barrier top as a function of the wavepacket center parameter, however. We suggest that a full semiclassical calculation, including nonclassical trajectories with complex energies, would improve the results.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    1995
  • Journal title
    Chemical Physics Letters
  • Record number

    1774296