Author/Authors :
Awaga، نويسنده , , Kunio and Sekine، نويسنده , , Taketoshi and Okawa، نويسنده , , Masaki Q. Fujita، نويسنده , , Wataru and Holmes، نويسنده , , Stephen M. and Girolami، نويسنده , , Gregory S.، نويسنده ,
Abstract :
The effects of high pressure, up to 1 GPa, on a Mn-based Prussian blue ferrimagnet, Mn3II[MnIII(CN)6]2·12H2O·1.7(CH3OH) with TN=29 K, were studied. The transition temperature gradually increases with an increase in pressure and becomes ∼40 K at 1 GPa. The pressure dependence of TN can be semi-quantitatively interpreted in terms of the shrinkage of the Mn–CN–Mn superexchange pathway.
