• Title of article

    Probing cluster structures with sensor molecules: methanol adsorbed onto gold clusters

  • Author/Authors

    Rousseau، نويسنده , , R. and Dietrich، نويسنده , , G. and Krückeberg، نويسنده , , S. and Lützenkirchen، نويسنده , , K. and Marx، نويسنده , , D. and Schweikhard، نويسنده , , L. and Walther، نويسنده , , C.، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 1998
  • Pages
    6
  • From page
    41
  • To page
    46
  • Abstract
    Structural, dynamical and electronic properties of the adducts formed by adsorbing methanol onto size-selected gold clusters are investigated using infrared multiple-photon dissociation spectroscopy of trapped Aun+CH3OH, n⩽15, in conjunction with Car–Parrinello calculations. The C–O stretching vibration of the attached sensor molecule changes discontinuously as a function of cluster size, which is traced back to a change in dimensionality of the cluster structure.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    1998
  • Journal title
    Chemical Physics Letters
  • Record number

    1775410