Title of article :
NMR of surfaces: sub-monolayer sensitivity with hyperpolarized 129Xe
Author/Authors :
Jنnsch، نويسنده , , H.J. and Hof، نويسنده , , T. J. Ruth، نويسنده , , U. and Schmidt، نويسنده , , J. and Stahl، نويسنده , , D. and Fick، نويسنده , , D.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 1998
Pages :
5
From page :
146
To page :
150
Abstract :
A typical laboratory single crystal of 1 cm2 surface area has about 1015 adsorption sites on the surface. The current paper shows that NMR signals can be obtained from sub-monolayer amounts of 129Xe adsorbates. For this, less than 1015 atoms of hyperpolarized 129Xe were studied in gaseous and condensed form in single shot experiments. The highest polarization achieved so far is 0.7. Analysis of the results shows that spectra from 1013 atoms can be obtained in reasonable time, thus opening single crystal surfaces to NMR investigations with conventional spectrometers.
Journal title :
Chemical Physics Letters
Serial Year :
1998
Journal title :
Chemical Physics Letters
Record number :
1775643
Link To Document :
بازگشت