Title of article :
Can an external magnetic field affect the thermal reaction of pentafluorobenzyl chloride with n-butyllithium in hexane?
Author/Authors :
Wakasa، نويسنده , , Masanobu and Hayashi، نويسنده , , Hisaharu، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2001
Pages :
7
From page :
493
To page :
499
Abstract :
The magnetic field effects reported in 1973 for the thermal reaction of pentafluorobenzyl chloride with n-butyllithium in hexane were re-examined at 23±3°C with modern techniques. Using a new reaction apparatus, which has an electromagnet (up to 14.9 kG) in a glove box under argon atmosphere (H2O and O2<1 ppm), we studied the magnetic field effects on the yields of final products of pentafluorophenylpentane and decafluorodiphenylethane in the absence and presence of an external magnetic field of 14.9 kG. No significant magnetic field effect was observed upon the yields of pentafluorophenylpentane and decafluorodiphenylethane under well-controlled conditions with sufficient repetitions.
Journal title :
Chemical Physics Letters
Serial Year :
2001
Journal title :
Chemical Physics Letters
Record number :
1776114
Link To Document :
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