• Title of article

    Can an external magnetic field affect the thermal reaction of pentafluorobenzyl chloride with n-butyllithium in hexane?

  • Author/Authors

    Wakasa، نويسنده , , Masanobu and Hayashi، نويسنده , , Hisaharu، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2001
  • Pages
    7
  • From page
    493
  • To page
    499
  • Abstract
    The magnetic field effects reported in 1973 for the thermal reaction of pentafluorobenzyl chloride with n-butyllithium in hexane were re-examined at 23±3°C with modern techniques. Using a new reaction apparatus, which has an electromagnet (up to 14.9 kG) in a glove box under argon atmosphere (H2O and O2<1 ppm), we studied the magnetic field effects on the yields of final products of pentafluorophenylpentane and decafluorodiphenylethane in the absence and presence of an external magnetic field of 14.9 kG. No significant magnetic field effect was observed upon the yields of pentafluorophenylpentane and decafluorodiphenylethane under well-controlled conditions with sufficient repetitions.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    2001
  • Journal title
    Chemical Physics Letters
  • Record number

    1776114