Author/Authors :
Kubozono، نويسنده , , Y. and Fujiki، نويسنده , , S. and Hiraoka، نويسنده , , K. and Urakawa، نويسنده , , T. and Takabayashi، نويسنده , , Y. and Kashino، نويسنده , , Chaitanya S. and Iwasa، نويسنده , , Y. and Kitagawa، نويسنده , , H. and Mitani، نويسنده , , Y.، نويسنده ,
Abstract :
Temperature dependence of Raman scattering in a pressure-induced superconductor Cs3C60 was studied under ambient pressure between 2 and 290 K. The contributions of the intramolecular vibration modes to electron–phonon coupling were evaluated by comparing the linewidths of the modes in Cs3C60 with those in pristine C60. The total electron–phonon coupling constant λ was ≈0.18, approximately one-third of the values for Rb3C60 and K3C60. Temperature-dependent Raman scattering in the superconductor Rb3C60 and a non-superconductor Rb6C60 was also measured for comparison.