Author/Authors :
OʹKeeffe، نويسنده , , Patrick and Ridley، نويسنده , , Trevor and Wang، نويسنده , , Shiliang and Lawley، نويسنده , , Kenneth P and Donovan، نويسنده , , Robert J، نويسنده ,
Abstract :
The previously unobserved O2(b 1Σ+g)+O(3PJ) spin-forbidden photodissociation channel of ozone is identified following absorption in the Huggins band (335–352 nm). The nascent O2(b 1Σ+g) photofragments are detected by two-colour resonance enhanced multiphoton ionisation (REMPI) via the d3sσg 1Πg Rydberg state.