Author/Authors :
von Helden، نويسنده , , G. and Holleman، نويسنده , , I. and Putter، نويسنده , , M. and van Roij، نويسنده , , A.J.A. and Meijer، نويسنده , , G.، نويسنده ,
Abstract :
Gas-phase C84 is resonantly excited using infrared (IR) radiation from a free electron laser. At specific wavelengths, strong ion signals are observed, resulting from thermionic emission of electrons by the fullerenes. The mass-selected ion yield is recorded as a function of IR frequency and the resulting spectrum yields information on the electronic ground state of the gas-phase molecule.