Title of article
On multiple solutions of the Fock-space coupled-cluster method
Author/Authors
Meissner، نويسنده , , Leszek، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1996
Pages
7
From page
244
To page
250
Abstract
Intermediate Hamiltonian techniques are used to investigate the problem of multiple solutions of the Fock-space coupled-cluster methods. Two intermediate Hamiltonian schemes are presented, based upon similarity transformations that unlike the wave operator formalism allow for following the complete eigenvalue problem. Solutions of the standard effective Hamiltonian formulation that requires iterative approaches to solve the equations are equivalently given by diagonalization of the intermediate Hamiltonian matrix representations. This procedure provides a systematic way of obtaining all possible solutions of the effective Hamiltonian scheme in all sectors higher than the lowest one.
Journal title
Chemical Physics Letters
Serial Year
1996
Journal title
Chemical Physics Letters
Record number
1777025
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