Author/Authors :
Su، نويسنده , , Hongmei and Yang، نويسنده , , Jixin and Zhong، نويسنده , , Jinxian and Kong، نويسنده , , Fanao، نويسنده ,
Abstract :
The reaction dynamics of methylene radical CH2(X̃ 3B1) with N2O was investigated by time-resolved Fourier transform infrared spectroscopy. Pure CH2(X̃ 3B1) radical was produced via laser photolysis of ketene at 351 nm. Nascent vibrationally excited products CO, NO and HCN were observed. Five reaction pathways and three possible reaction intermediates are proposed.