Author/Authors :
Rogers، نويسنده , , Leon J. and Ashfold، نويسنده , , Michael N.R. and Matsumi، نويسنده , , Yutaka and Kawasaki، نويسنده , , Masahiro and Whitaker، نويسنده , , Benjamin J.، نويسنده ,
Abstract :
The photodissociation of iodine monochloride following excitation at 235 nm, within its second absorption band, has been investigated further using ion imaging methods to monitor the Cl(2P°32) and Cl∗(2P°12) atomic products. The angular distributions of these products are found to be characterised by anisotropy parameters, β = 1.8 ± 0.2 and −1.0 ± 0.1 for the Cl and Cl∗ products, respectively, whilst the measured Cl/Cl∗ translational energies indicate the involvement of the two product channels: ICl + hν(λ = 235 nm) → Cl + I∗ (2P°12) and Cl∗ + I(2P°32).
