Author/Authors :
Ishiuchi، نويسنده , , Shun-ichi and Sakai، نويسنده , , Makoto and Daigoku، نويسنده , , Kota and Ueda، نويسنده , , Tadashi and Yamanaka، نويسنده , , Takaya and Hashimoto، نويسنده , , Kenro and Fujii، نويسنده , , Masaaki، نويسنده ,
Abstract :
Picosecond time-resolved IR spectra of phenol–(NH3)3 have been measured by UV–IR–UV ion dip spectroscopy for the first time. It was found that the time-evolution of two vibrational bands at 3180 and 3250 cm−1 is different from each other. The results show that two transient species are generated from the photo-excited phenol–(NH3)3 cluster. From ab initio calculation, the transient species are assigned to two isomers of (NH3)2NH4.
